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Laser-Induced Breakdown Spectroscopy (LIBS)

Laser-Induced Breakdown Spectroscopy (LIBS)

Asia Mattelab is the sole distributor for Lightgo Laser Induced Breakdown Spectroscopy (LIBS) in Singapore and South East Asia (Malaysia, Thailand, Vietnam, Indonesia, Philippines). Lightigo s.r.o. is a start-up company focused on the development and production of the analytical instruments for the Laser-Induced Breakdown Spectroscopy, one of today’s most promising technique of elemental analysis. Lightigo was founded in August 2019 by the researchers and hardware developers who have the long-term experience with the R&D in the field of LIBS.

Laser Induced Breakdown Spectroscopy (LIBS) is a rapid chemical analysis technology that uses a short laser pulse to create a micro-plasma on the sample surface. This analytical technique offers many compelling advantages compared to other elemental analysis techniques. A typical detection limit of LIBS for heavy metallic elements is in the low-PPM range. LIBS is applicable to a wide range of sample matrices that include metals, semiconductors, glasses, biological tissues, insulators, plastics, soils, plants, soils, thin-paint coating, and electronic materials.

FireFly is an analytical instrument for rapid multi-elemental analysis and chemical imaging. It utilises the Laser-Induced Breakdown Spectroscopy (LIBS) - one of today's most promising technique of elemental analysis. With FireFly, you can easily apply the key benefits of LIBS technology in your elemental analysis application. The FireFly is a robust and easy to use system. It allows fast multi-elemental analysis of solid samples without the need of complicated sample preparation. You obtain results within seconds.

Main Characteristic for FireFly are :

  • Solid samples
  • 1-100 ppm limits of detection
  • 10-150 um spatial resolution
  • Chemical imaging and depth profiling
  • 100 x 100 mm scanning area
  • 100 Hz scanning rate
  • Efficient technology, low operational cost
  • Wide range of elements, including Li, Be, Mg, Na, N, C

Meet The FireFly


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Flexibility and Capability of The FireFly are Numerous

Metal
  • Depth-profiling and characterization of coatings
  • Homogeneity check, defectoscopy
  • Quantification of carbon and alloying elements in steel
  • Aluminum sorting, scrap sorting
  • Determination of corrosion
Tissues
  • Tag-LIBS
  • indirect detection of biomarkers through nanoparticle tags
  • Metallomics in soft tissue, cancer tissue analysis
  • Chemical imaging of hard tissues (bones and teeth)
  • Biology
    • Correlation of elemental distribution and chlorophyll content
    • Detection of heavy metals and toxic elements in plants
    • Diagnostic of fertilization, detection of P, K N, ...
    • Determination of nutrition elements in plants/soils
    • Detection of microplastic pollution in biota
    Plastic
    • Classification of polymer, including the combination with Raman spectroscopy
    • Circular economy: detection of heavy metals in recycled plastic material
    • Determination of toxic elements in packing materials, toys, etc
    • Input/output quality check
    Geology
    • Online classification of rocks, minerals, and their variations
    • Provenance study through unique chemical fingerprints
    • Structural analysis of rocks, investigation of inclusion
    • Correlative imaging with computed tomography and SEM
    • Gemstone validation

    Key Benefit

    Take the experiences and requirements of the users, who work with the elemental analysis on the daily basis. Mix in the unique benefits of LIBS technology and you get the FireFly

    Clear Sample View

    No more blurry images ! Laser ablation optics are combined with dedicated microscopy sample view optics to provide you with clear and sharp images of a sample being analyzed

    Illumination is of a dual-type to adapt to the wide spectra or sample types :
    • Colinear LED Illumination
    • Difused LED Illumination

    Quick Targeting

    You will never get lost in magnified sample surface while searching for desired spot for the analysis
    • Switch between multiple Fields of View
    • Create whole-stage overview image
    • Move the sample simply by mouse button click on desired spot

    Measurement Modes

    Wheter you want to check few spots dispersed on the samole or perform large area scan, FireFly has right tool

    • Multi-Spot
    • Schedule a series of spots and start the measurement at once
    • Mapping
    • Scan the area to visualize concentrations of multiple elemets
    • Line Scan
    • Scan along the line, boundary or vein by drawing a polygonial line

    Depth Profiling

    For each spot, a total number of laser pulses and measurements can be set. Resulting group of spectra from each spot can be used for
    • Accumulation for improving the signal to noise ratio thus improving the limits of detection
    • Multi-layer depth analysis to determine elemental composition of individual depth layers of the material

    Spectra and Maps

    Explore the results in a form of spectra and chemical maps utilizing flexible and intuitive tools.

    • Pan, Scroll, Scale and change color histogram
    • Use Max, Mean, SDEV and Peak overlay curves to simplify the quick spectra evaluation
    • Quickly re-draw the map to display the distribution of concentration of a different element
    • Filter spectra by unique metadata
    • Show atomic emission line from LIBS database
    • Export to ASCI, Bitmap to optimize data file

    Mapping Capabilities

    Single map scan collects complete analytical data about the elemental composition. Creating the map for any present element is a matter of moment

    • Area up to 100 x 100 mm
    • Scanning rate up to 100 Hz, full UV-NIR range spectra
    • Resolution 10 nm minimal, 30-100 nm typical
    • Duration, 1 square cm in 8 minutes, 50 nm step size - 512 DPI

    Technical Highlights


    Laser Wavelength

    With the FireFly you can always select laser wavelength, which is optimal for your current applications.

    • Do you need a smaller spot size or high absroption ?
    • Select UV 266 nm
    • High pulse energy is the priority ?
    • Switch to IR 1064 nm
    • Or simply utilize versatile ?
    • Switch to VIS 532 nm

    Multiple Objectives

    Different optical task require different objectives in order to be solved without any compromises :

    • Multiple plan-apochromatic objectives for sharp view with varios magnifications
    • High damage-threshold objectives corrected for precise laser focus etiher in micro-focus or long-depth of focus versions
    FireFly has them all - moreover, mounted on motorized objective turret controlled via single button click in SW !

    Laser Focusing

    FireFly can handle non-flat samples, which otherwise might cause laser defocus and signal fluctuations during the mapping.

    • Autofocus, even during the mapping
    • Dedicated long depth of focus (DOF) objective
    Motorized focusing stage can be used to change the laser spotsize on the sample directly from the control software.
    • Less than 20 nm spot size can be achieved by aperture imaging technique

    Gas Modules

    Gas purge
    • Cleans the sample to avoid smearing of the signal to surrounding spots on the chemical map
    • Creates local inert gas atmosphere to significantly impove the limist of detection
    Dust extraction
    • Extracts potentially toxic vapors of laser ablation
    • Keeps the optomechanical components clean
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    Core Components

    Lasers, spectrometers and detectors are the core components of every LIBS system. There are multiple configuration of which we always select the optimal one based on customer requirements

    Lasers

    DPSS Nd:YAG  pulsed laser is used for including the plasma

    • Modern and efficient Diode-Pumping (DPSS)
    • Longer life-time, and better stabiility compared to the traditional FPSS lasers
    • Effeciency of the DPSS results in a lower power consumption, quite run and simple air cooling
    • 24/7 operation capability
    • Motorized pulse regulation, energy meter and wavelength conversion is available

    Spectrometer

    Plasma radiation is captured by the UV-NIR collecting optics and spectrally decomposed by the spectrometer

    • Compact multichannel Czerny-Turner spectrometers
    • High performance Echelle spectrometers

    Detector

    Radiation is captured by the detector and converted into the spectra

    • Basic CMOS detectors
    • Advanced sCMOS or EMCCD detectors
    • Specialized intensified sCMOS/CCD detectors
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    Miscellaneous


    Users Roles



    It is possible to differentiate individual users. Different roles has different rights in control software

    Configuration Profiles



    Various system configuration can be saved and loaded thus easily used next time

    Self Diagnostic



    Initial measurement of standard highly homogenized sample is used to track and visualize system performance

    Measurement Guides



    Step-by-step guides for most common measurement scenarios.

    Automated Log



    Activity of the user is automatically recorder, can be browsed and exported.

    External Synchronization



    Internal synchronization clock can be synchronized both IN and OUT to external instruments utilizing TTL pulses and BNC connectors.
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    FireFly Exterior


    What about The Ergonomy ?


    Every obstacle counts when analyzing for hours...


    We are aware of this, so we have put our effort to design an efficient and comfortable work position with easy chamber/sample access.

    • A spacious front window enables one to observe the interaction area and laser ablation from the front.
    • Side windows enable the user to see into the chamber while sitting in front of PC.
    • The Chamber door handle is perfectly accessible directly from the PC. Just extend your arm and open the wide chamber door to comfortably handle the sample.
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    SyncRay - Digital Delay Generator

    Your nifty box for precise synchronization


    Syncray is a digital delay generator designed to create and manipulate delays or echoes of sound signals. The device takes an input audio signal and reproduces it after a specified amount of time, creating a repeated, delayed version of the original sound.

    Syncray offers various parameters and controls to shape the delay effect. It allows the user to adjust the delay time, determining how long the repetition occurs after the initial sound. Additionally, it provides options to control the feedback, which determines the number of repetitions and their decay over time. This feature adds depth and texture to the delayed sound.

    Moreover, Syncray may have additional features like modulation, filtering, and synchronization capabilities. Modulation introduces subtle variations to the delayed sound, creating a more dynamic and evolving effect. Filtering allows the user to shape the frequency content of the delay, emphasizing or attenuating specific ranges. Synchronization enables the device to synchronize the delay time to a tempo or external clock source, ensuring precise rhythmic repetitions.

    Precise analysis requires precise synchronization. With the SyncRay, our compact Digital Pulse (Delay) Generator (DPG), you can synchronize up to 5 instruments with nanosecond precision. SyncRay has been designed as a compromise between cheap DPGs, which lacks some important features and more advanced DPGs, which are too big and/or too expensive.

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    3-axes Motorized Stage for LIBS

    A 3-axes motorized stage provides researchers, engineers, and technicians with a reliable and versatile platform for positioning and manipulating objects in a three-dimensional space, facilitating various scientific, industrial, and technological applications. 

    Do not waste your time with the manual sample movement, which is slow, inaccurate, and hardly repeatable.3-axis motorised stage is beneficial for any application where frequent sample movement is required: optical microscopy, analytical techniques (Raman, LA-ICP, XRF, LIBS, ...), material processing methods, and many others.

    Specification

    • Travel range: X × Y × Z: 100 × 100 × 70 mm
    • Step resolution: <1 μm
    • Bi-directional repeatability (RMS): ±0.40 μm
    • C++ control libraries for OEM integration

    Software features

    • Relative / absolute movement to a coordinate
    • Automated movement based on the series of coordinates for the mapping (chemical imaging)
    • Batch import / export coordinates
    • Wait time and Trigger-out after reaching set coordinate
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    Custom Product

    Where quick elemental analysis is desired, the LIBS technique can save time, money and material resources.


    Wide spectrum of industrial fields can benefit from the LIBS technology. From laboratory LIBS systems, in-situ compact LIBS instruments or stand-off systems capable of material analysis at the distance of units of meters. R&D team of Lightigo, in close cooperation with Laboratory of Laser Spectroscopy on CEITEC BUT is capable of custom development of the LIBS systems based on customer’s needs.

    Application examples

    • Depth profiling of multilayer materials
    • Quality control of input / output materials
    • Chemical mapping of heterogenic materials
    • Detection of metallic / heavy / toxic elements
    • Material sorting
    • etc.
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